Sodium ion sensitive microelectrode based on a p-tert-butylcalix[4]arene ethyl ester - Université Jean-Monnet-Saint-Étienne Accéder directement au contenu
Article Dans Une Revue Sensors and Actuators B: Chemical Année : 2008

Sodium ion sensitive microelectrode based on a p-tert-butylcalix[4]arene ethyl ester

Résumé

Planar sodium-selective potentiometric microelectrodes with a conducting polymer (polypyrrole doped with cobaltabis(dicarbollide) ions ([3,3'-Co(1,2-C2B9H11)2]-)) as solid contact layer between the polymeric sensitive membrane and the platinum substrate have been constructed. The p-tert-butylcalix[4]arene ethyl ester was used as ionophore for sodium recognition. The microelectrode shows a linear response for Na+ concentrations between 3.0×10-6 M and 1.0×10-1 M with a Nernstian slope of 58.65 ± 2 mV per decade and a detection limit of 1.45×10-6 M. The response time was 14 s, and the electrode is suitable for use within the pH range of 3-10.

Domaines

Matériaux
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Dates et versions

ujm-00350754 , version 1 (07-01-2009)

Identifiants

  • HAL Id : ujm-00350754 , version 1

Citer

I. Marques de Oliveira, D. Risco, F. Vocanson, E. Crespo, F. Teixidor, et al.. Sodium ion sensitive microelectrode based on a p-tert-butylcalix[4]arene ethyl ester. Sensors and Actuators B: Chemical, 2008, 130 (1), pp.295. ⟨ujm-00350754⟩
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