Novel Ca2+ interdigited microelectrodes based on self-assembled monolayers of a new calix[4]arene crown-5 derivate

M.R. Sergio (1) , I. Marques de Oliveira (1) , N. Zine (1) , Francis Vocanson (2) , J. Bausells (3) , Josep Samitier (1) , Abdelhamid Errachid (1)

1 Lab NanoBioEngn
2 LHC - Laboratoire Hubert Curien [Saint Etienne]
3 CNM - Centro Nacional de Microelectronica [Spain]

A kinetic study of the ionic interaction along the molecular recognition process of a self-assembled monolayer (SAM) based on calixarene molecules with calcium ion is reported. For this study we have used interdigited electrodes (IDEs) developed with silicon technology, functionalized with a SAM of new calix[4]arene derivative. Variations in conductance due to the changes in the charge-transfer resistance produced by the ion recognition are measured using a Lock-In Amplifier.

Keywords: calixarenes; interdigited electrodes; conductimetric measurements

Domains: Chemical Sciences; Material chemistry

M.R. Sergio, I. Marques de Oliveira, N. Zine, Francis Vocanson, J. Bausells, et al.. Novel Ca2+ interdigited microelectrodes based on self-assembled monolayers of a new calix[4]arene crown-5 derivate. Eurosensors XXII, 2008, Dresde, Germany. ⟨ujm-00350897⟩