USE OF THE CALIX[4]ARENE PLATFORM TO ELABORATE NEW REDOX MOLECULAR SWITCHES

Ulrich Darbost (1) , E. Jeanneau (2) , I. Bonnamour (1) , C. Felix (1) , Francis Vocanson (3) , C. Bucher (4) , Catherine Belle (4) , Guy Royal (4)

1 ICBMS - Institut de Chimie et Biochimie Moléculaires et Supramoléculaires
2 LMI - Laboratoire des Multimatériaux et Interfaces
3 LHC - Laboratoire Hubert Curien
4 DCM - Département de Chimie Moléculaire

Two different types of molecular switches based on new calix[4]arenes have been obtained. Concerning the [Dicyano-Diimidazole/Copper] complexes, the auto-reduction after few minutes of the oxidized state makes the system comparable to a time switch. On the other side, the [Diquino-Diimidazole/Copper] complex is a bi-stable reversible system. The gap of potential observed (0.9 V) between oxydation and reduction wave induces an hysteresis property and consequently makes this system a new performant two states molecular switch based on calix[4]arene. The [Diquino-Diimidazole/Copper] complex is a perfect model of a two states light switch

Domaines: Matériaux

Ulrich Darbost, E. Jeanneau, I. Bonnamour, C. Felix, Francis Vocanson, et al.. USE OF THE CALIX[4]ARENE PLATFORM TO ELABORATE NEW REDOX MOLECULAR SWITCHES. International Symposium on Macrocyclic and Supramolecular Chemistry, Jul 2008, Las Vegas, United States. ⟨ujm-00350927⟩